The following possible mechanisms, giving rise to a lower bound to Darcy's Law for water flow, have been identified;
Mechanism |
Darcy's Law condition not satisfied |
| Streaming potential gives rise to counter current Flow | The porous media is inert |
Quasi-crystalline arrangement of water molecules |
The displacing fluid behaviour is Newtonian The porous media is inert |
| Non-Newtonian behaviour |
The displacing fluid behaviour is Newtonian |
| Geometric rearrangement of the pore matrix (movement of fines) | The pore geometry is stable |
Electro-chemical forces at the grain-water interface could have a role in all these mechanisms.
The book 'Introduction - Colloid and Surface Chemistry' by Duncan J Shaw is a useful reference for those wishing to develop their knowledge in this area.